Description

This course will describe aspects of both experimental and theoretical advanced vibrational and rotational spectroscopy. It will consider mainly gas phase spectroscopy but with links to jet expansion and matrix techniques. The focus will be on the use of these spectroscopies to gain information of the underlying physical chemistry and spectroscopic identification. Quantum chemical calculations will be used as a tool to explain and predict spectra. Theory of molecular vibration within the normal and local mode model will be covered. Experimental techniques used to observe vibrational transitions including the weak overtone transitions associated with the highly vibrational excited molecules will be explained. The main aim is that student will be able to critically read literature in the areas covered.

Knowledge:

• Theory of rotational and vibrational transitions.
• The different experimental techniques used in gas phase spectroscopy. Some typical acronym: IR and Raman will be understood.
• Experience with analyzing experimental IR and Raman measurements and the use of quantum chemical calculations to facilitate this.

Skills:

• Describe different techniques, instruments and the theory behind them.

Competences:

• Be able to critically read papers in current international physical chemistry journals.
• Assess the usefulness of different spectroscopic techniques to solve different research questions.
• Apply the theoretical knowledge and analytical skills.

Recommended qualifications

Basic competencies in mathematics, physical chemistry, quantum chemistry and spectroscopy are necessary. Quantum chemistry calculations will be used.



Academic qualifications equivalent to a BSc degree is recommended.